Aromaticity and Extrusion of Benzenoids Linked to [ <i>o</i> ‐COSAN] <sup>−</sup> : Clar Has the Answer

نویسندگان

چکیده

Benzene and pyrene can be synthetically linked to [o-COSAN]− keeping their aromaticity. In contrast, naphthalene anthracene are extruded in the same reaction. We have proven that extrusion is only favorable if number of Clar's π-sextets remains constant. Thus, Clar has answer whether an attached polycyclic aromatic hydrocarbon or not.

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ژورنال

عنوان ژورنال: Angewandte Chemie

سال: 2022

ISSN: ['1521-3773', '1433-7851', '0570-0833']

DOI: https://doi.org/10.1002/ange.202200672